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Here is a sample word list. These are some of the most challenging SAT Vocab words.

Simian-Relating to monkeys or apes
Lintel-Architectural support for a building or window
Finial-Decorative element meant for honor
Enclave-Isolated/separated group of people
Bagatelle-A task or piece that is trivial, light, or non-essential
Subordinate-Person under the authority of another
Chauvinistic-Feeling superior because of race or gender
Oblivious-Unaware, disconnected
Hidebound-Stubborn, unwilling to change
Effete-Related to feminine characteristics
Ribald-Inappropriate/vulgar in a humorous way
Supine-Lying face up
Caterwaul-Shrill/wailing noise
Vassal-Related to feudal times
Verisimilitude-The appearance of being real
Miniscule-Tiny
Polarize-To separate into 2 sides of an issue (political, economic, etc…)
Paternalism-Political system of restricting the freedoms of lower people
Schism-Separation